p-block elements are those in which the valence electron enters in the p-orbital. Here we will discuss the general characteristics of p-block elements.
What are p-Block elements
- These elements are those in which the valence electron enters in the p-orbital.
- p-subshell has 3 degenerate orbitals. Therefore it can accommodate a maximum of 6 electrons.
- It includes the elements from group 13 to group 18.
- These groups receive the last electron in 2p, 3p, 4p, 5p,6p orbitals respectively.
- s-orbital of the outermost shell is already complete. Thereafter, the filling of p-orbital occurs.
- The total elements are 36 p-block elements.
General electronic configuration of p-block
- General electronic configuration of these block elements : ns2 np1-6 where n = 2 – 7
- The elements of group 18 are noble gases. They have ns2 np6 electronic configuration.
- Elements of group 17 are halogens while group 16 are chalcogens. These 2 groups are having highly negative electron gain enthalpy.
- Representative elements or main group elements consists of s and p-block elements.
- s-block consists of alkali metals and alkaline earth metals.
General characteristics of p-block
- These block elements include both metals and non-metals. Metallic character increases from top to bottom. Non-metallic character increases from left to right.
- The ionisation energy of these block elements are higher than s-block elements.
- p-block mostly forms covalent compounds.
- Some elements of this group show variable oxidation states.
- The oxidising character increases from left to right in the period.
- Reducing character increases from top to bottom in the group.
- These block elements form acidic, basic and amphoteric oxides.
- If the IE of the element is high, its oxide is acidic. Higher the IE , stronger is the acid.
- B2O3 – weakly acidic Al2O3 – amphoteric Ga2O3 – amphoteric In2O3 – Basic Tl2O3 – strongly basic ( group 13 )
- B2O3 + 3H2O ➡️ 2H3BO3 or 2B (OH)3 ( orthoboric acid )
- Al2O3 + 2NaOH ➡️ 2NaAlO2 ( sodium meta-aluminate ) +H2O
- Al2O3 + 6HCl ➡️ 2 AlCl3 + 3H2O
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