d-block elements are those in which the last electron enters the d-orbital of the valence shell. Here, we will discuss about the d-block elements.
What are d-block Elements
- These are elements in which last electron enters any one of the 5 orbitals of their respective penultimate shell.
- General outer electronic configuration : (n-1) d1-10 ns 0-2 where n= 4 – 7
- There are 10 groups from group 3 to group 12
- d-block have the properties which lies in between s-block and p-block block elements. Therefore, they are known as transition elements.
Transition series of d-block
- The first transition series forms 4th period. It contains 10 elements from Scandium to Zinc ( 21Sc – 30 Zn ). Here, is the progressive filling of 3d orbitals.
- The second transition series forms 5th period. It contains 10 elements from Ytterium to Cadmium ( 39Y – 48Cd ). Here, is the progressive filling of 4d orbitals.
- The Third transition series forms 6th period. It contains 10 elements from Lanthanum, and Hafnium to Mercury ( 72Hf-80Hg ). Here, is the progressive filling of 5d orbitals.
- The fourth transition series forms 7th period. It contains 10 elements from actinium and Rutherfordium (104) to (112) Copernicium. Here, is the progressive filling of 6d orbitals.
- There are groups 3 to 12 in which the last electron enters the d orbitals of their respective penultimate shells.
- Therefore, there are 40 d elements in the periodic table.
General characteristics of d-block elements
- These elements are hard, malleable and ductile metals with high melting and boiling points.
- These metals show IE between s and p block elements.
- They show variable Oxidation state.
- They form ionic as well as covalent compounds.
- These compounds are coloured and paramagnetic in nature.
- Transition metals form co-ordination complexes.
- There are 3 exceptions which do not behave as transition elements. Zn, Cd and Hg has EC (n-1)d10 ns2
- Most of the transition elements form alloys.
- They are good conductor of heat and electricity.
- Their compounds acts as catalysts.
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